Product ID:SUPELPREME-HC KIT PHENOLS MIX, 48909
MSDS Date:06/07/1988
FSC:6850
NIIN:00N018231
Kit Part:Y
MSDS Number: BNCQL

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

ORAL(RAT)384 MG/KG.

CAS: 108-95-2

RTECS: SJ3325000

Fraction By Weight: 0.2%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ORAL(RAT)2524

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 98%

OSHA PEL 500 PPM, 1000C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ORAL(RAT)50

CAS: 87-86-5

RTECS: SM6300000

Fraction By Weight: 0.2%

OSHA PEL 0.5 MG/M3, S

ACGIH TLV: 0.5 MG/M3, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ORAL(RAT)3400 MG/KG

CAS: 105-67-9

RTECS: ZE5600000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PHENOL,2,4-DICHLORO-; (2,4-DICHLOROPHENOL).

CAS: 120-83-2

RTECS: SK8575000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ORAL(RAT)30

CAS: 51-28-5

RTECS: SL2800000

Fraction By Weight: 0.2%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHENOL,2,4,6-TRICHLORO-; (2,4,6-TRICHLOROPHENOL).

CAS: 88-06-2

RTECS: SN1575000

Fraction By Weight: 0.2%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

M-CRESOL,4-CHLORO-; (4-CHLORO-3-METHYLPHENOL).

CAS: 59-50-7

RTECS: GO7100000

Fraction By Weight: 0.2%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ORAL(RAT)670

CAS: 95-57-8

RTECS: SK2625000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ORAL(RAT)2828 MG/KG.

CAS: 88-75-5

RTECS: SM2100000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ORAL(RAT)350 MG/KG.

CAS: 100-02-7

RTECS: SM2275000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

O-CRESOL,4,6-DINITRO-; (2-METHYL-4,6-DINITROPHENOL).

CAS: 534-52-1

RTECS: GO9625000

Fraction By Weight: 0.2%

OSHA PEL 0.2 MG/M3, S

ACGIH TLV: 0.2 MG/M3, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CAUSES CANCER. IRRITATE EYES/SKIN.
NAUS/ DIZZ. SEVERAL CHRONIC INHAL STUDIES RPTD BY NIOSH REVEALED
THAT TEST ANIMALS EXPOSED TO METHYLENE CHLORIDE CONC AS HIGH AS
10,000PPM SHOWED SLIGHT LIVER/KIDNEY CHANGES. METHYLENE CHLORIDE
HAS BEEN SHOWN TO INCR RATE OF SPON OCCURING MALIGNANT TUMORS IN 1
STRAIN (EFTS OF OVEREXP)
Explanation of Carcinogenicity:TRICHLOROPHENOL (2,4,6); NTP GROUP 2.
METHYLENE CHLORIDE: IARC GROUP 2B, NTP GROUP 2, ACGIH GROUP A2.
Effects of Overexposure:HLTH HAZ:OF LAB MICE & BENIGN TUMORS IN LAB
RATS. CHLOROCARBON MATLS HAVE PRDCD SENSIT OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT
FOR LIFE-SUSTAINING IN HUMANS ACUTELY OR CHRONICALLY EXPOS TO(SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:CONT PHYS. SKIN:PROMPTLY WASH W/MILD SOAP & LG VOL OF
H2O. CONT PHYS. INHAL:IMMED MOVE TO FRESH AIR. GIVE O2 IF BRTHG IS
LABORED. IF BRTHG STOPS, GIVE ARTF RESP. CONT PHYS. INGEST: NEVER
GIVE ANY THING BY MOUTH TO AN UNCON PERSON. NEVER TRY TO MAKE AN
UNCON PERSON VOMIT. GIVE SYRUP OF IPECAC. IMMED CONT PHYS.

Lower Limits:12.0%
Upper Limits:19.0%
Extinguishing Media:THIS MATERIAL IS NOT FLAMMABLE. DETERMINED BY
SUPPORTING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT WHEN FIGHTING A CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:FOLLOW TOX VAP ARE FORMED WHEN MATL
HEATED TO DECOMP: HCL, OXIDES OF NITROGEN. PHOSGENE .

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. FLUSH WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFERIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM BASES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS. NO
SMOKING IN AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC
WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR UV RADIATION MAY
CAUSE FORMATION O F HCL AND/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN EXHAUST HOOD.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: TO CHLOROCARBONS .

HCC:T4
Boiling Pt:B.P. Text:104F,40C
Vapor Pres:350MM
Solubility in Water:1.3
Appearance and Odor:CLEAR LIQUID, CHLOROFORM-LIKE ODOR.
Percent Volatiles by Volume:98

Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS, CHEMICALLY ACTIVE METALS SUCH AS
ALUMINUM OR MAGNESIUM POWDERS.
Hazardous Decomposition Products:HCL, OXIDES OF NITROGEN. PHOSGENE .

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.